Details

Item Description Structure
Catalog 8394 CAS 114615-82-6
Product Name Tetrapropylammonium perruthenate
Other Name TPAP
Purity 97% ee NA
Molecular Formula C12H28NO4Ru
Molecular Weight 351.43
Color and Form green
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 165C
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemists most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions
1. Synlett, 948, (2006)
2. Oxidation of hydroxyl-substituted organotrifluoroborates. J. Am. Chem. Soc. 128, 9634, (2006)
3. Synthesis 7, 639-666, (1994)
Synthesis, 639, (1994)
Aldrichimica Acta 23, 13, (1990)
Tetrahedron Lett. 45, 303-308, (2004)
Merck 14,10463
Fieser 14,302 / Fieser 16,325
Structure Index 1, 60:B:1

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Other 1,4-Bis(diphenylphosphino)butane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, dichloromethane adduct,98% 59831-02-6 Dichloro(1,3-bis(diphenylphosphino)propane)palladium(II),98% (DPPP)PdCl2 157772-65-1 1,1'-Bis(di-i-propylphosphino)ferrocene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate,98% 13965-03-2 trans-Dichlorobis(triphenylphosphine)palladium(II),98% (PPh3)2PdCl2 99326-34-8 1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate,98% 14588-08-0 Diacetatobis(triphenylphosphine)palladium(II),98% (PPh3)2Pd(OAc)2 120967-70-6 1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate 14221-01-3 Tetrakis(triphenylphosphine)palladium (0),98% Pd(PPh3)4 73468-85-6 Hydroxy(1,5-cyclooctadiene)rhodium(I) dimer,97% [Rh(COD)(OH)]2 32005-36-0 Bis(dibenzylideneacetone)palladium (0), Pd(dba)2 12279-09-3 Chlorobis(cyclooctene)rhodium(I) dimer,98% 51364-51-3 Tris(dibenzylideneacetone)dipalladium (0), Pd2(dba)3 34767-55-0 Acetylacetonatobis(cyclooctene)rhodium(I),97% 52522-40-4 Tris(dibenzylideneacetone)dipalladium (0) chloroform adduct, Pd2(dba)3 CHCl3 36620-11-8 Bis(norbornadiene)rhodium(I) tetrafluoroborate,96% [Rh(NBD)2]+BF4- 14592-56-4 Dichlorobis(acetonitrile)palladium(II),98% (CH3CN)2PdCl2 12257-42-0 Chloronorbornadiene rhodium(I) dimer,98% [Rh(NBD)Cl]2 12081-16-2 Chlorobis(ethylene)rhodium(I) dimer,98% [Rh(C2H4)2Cl]2 12107-56-1 Dichloro(1,5-cyclooctadiene)palladium(II),98% (COD)PdCl2 12082-47-2 Acetylacetonatobis(ethylene)rhodium(I),98% 14267-08-4 cis-Dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II),98% 178879-60-2 Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(R-DOSP)4 3375-31-3 Palladium(II) acetate,98% Pd3(OAc)6 179162-34-6 Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(S-DOSP)4 42196-31-6 Palladium(II) trifluoroacetate,97% Pd(CF3COO)2 12354-85-7 Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer,98% (Cp*RhCl2)2 115826-95-4 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),98% (R-BINAP)PdCl2 14284-92-5 Rhodium(III) acetylacetonate,98% Rh(CH3COCHCOCH3)3 127593-28-6 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),98% (S-BINAP)PdCl2 17185-29-4 Hydridocarbonyltris(triphenylphosphine)rhodium(I),98% 172418-32-5 trans-Di(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II),97% 13938-94-8 Chlorocarbonylbis(triphenylphosphine)rhodium(I),98% 31277-98-2 Bis[1,2-bis(diphenylphosphino)ethane]palladium (0),98% Pd(DPPE)2 14523-22-9 Chlorodicarbonylrhodium(I) dimer 444910-17-2 Dichloro(di-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II),97% 14874-82-9 Dicarbonylacetylacetonato rhodium(I),98% 14024-61-4 Palladium(II) acetylacetonate,98% 31126-95-1 Rhodium(II) trifluoroacetate dimer, Rh2(CF3COO)4 113822-11-0 cis-Dimethyl(N,N,N',N'-tetramethylethylenediamine)palladium(II),98% 10/1/7647 Palladium(II) chloride,98% PdCl2 13444-94-5 Palladium(II) bromide,98% PdBr2 7790-38-7 Palladium(II) iodide,98% PdI2 14220-64-5 Dichlorobis(benzonitrile)palladium(II),98% (C6H5CN)2PdCl2 205319-10-4 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II),98% 185812-86-6 Di-bromobis(tri-t-butylphosphino)dipalladium(I) 33309-88-5 Bis(tricyclohexylphosphine)palladium (0),98% Pd(PCy3)2 917511-90-1 Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct,98% 215788-65-1 Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium (II),98% 123333-45-9 [P,P'-1,3-Bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium (0)