138517-61-0 (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand

Item Description

Structure

Catalog

8103

CAS

138517-61-0

Product Name

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl)

Other Name

(R,R)-DACH-Phenyl Trost Ligand;TROST LIGAND;(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1R,2R)-(+)-1,2-TROST LIGAND;(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphoshinobenzoyl);(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(R,R)-DACH-PhenylTrostLigand;(R,R)-DACH-phenyl Trost ligand;(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl;(1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane

Purity

98%

99%

Molecular Formula

C44H40N2O2P2

Molecular Weight

690.76

Color and Form

white to off-white pwdr.

Package

5g/10g and more Bulk Ordering Package

Solubility

Melting point

134-136C, spec. rotation +130 (c 1.0, methanol)

Stability

Yes

Risk

36/37/38

Safety

26-36/37/39

Hazard

spectrometry

Conforms to structure

HPLC

Conforms to structure

Note

Only for research purposes only

Technical Note

Technical Note:
1. The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon,
nitrogen, oxygen, sulfur , and fluorides nucleophiles.
References:
1. Angew. Chem., Int. Ed. 1997, 36, 2635.
2. J. Am. Chem. Soc. 1995, 117, 7246.
3. J. Am. Chem. Soc. 2011, 133, 20611.
4. Angew. Chem., Int. Ed. 1996, 35, 99.
5 Tetrahedron Lett., 1998, 39, 1713.
6. Org. Lett., 2007, 9, 2357.
7. J. Am. Chem. Soc., 1998, 120, 815.
8. J. Am. Chem. Soc., 2003, 125, 6066.
9. Tetrahedron Lett., 2000, 41, 3809.
10. J. Am. Chem. Soc., 2010, 132, 17402.

CIF PRICE

5g/ $0.00 10g/ $ 0.00 kg/$0.00

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