Details

Item Description Structure
Catalog 8190 CAS 162291-02-3
Product Name (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct
Other Name (S)-(R)-JOSIPHOS
Purity 97% ee 99%
Molecular Formula C36H44FeP2
Molecular Weight 594.59?
Color and Form Get details by COA
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point NA
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
Asymmetric hydrogenation of ketones and phosphinylketimines.
Michael addition of Grignard reagents to ",$-unsaturated esters and thioesters.
Boration of ",$-unsaturated esters and nitriles.
Reaction of aryl halides with ammonia.
Cu-catalyzed reduction of activated C=C bonds with PMHS.
Regio- and enantioselective hydroboration of vinyl arenes.
Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
Ligand for the Rh catalyzed synthesis of lactones.
Ligand for the Cu-catalyzed synthesis of syn and anti -amino alcohols

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