Details

Item Description Structure
Catalog 8191 CAS 184095-69-0
Product Name (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
Other Name (R,R)-1-[1-[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]ETHYL]-2-(DIPHENYLPHOSPHINO)FERROCENE;(R)-(-)-1-((S)-2-(DIPHENYLPHOSPHINO)FERROCENYL)ETHYLBIS(3,5-DIMETHYLPHENYL)PHOSPHINE;(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE;(R)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI(3,5-XYLYL)PHOSPHINE;(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine,min.97%;(r,r)-1-{1-[bis(3,5-dimethylphenyl)phosphino]ethyl}-2-(diphenylphosphino)ferrocene (acc to cas);(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO) FERROCENYL]ETHYLDI-3,5-XYLYLPHOSPHINE, MIN. 97%
Purity 97% ee 99%
Molecular Formula C40H40FeP2
Molecular Weight 638.54
Color and Form Get details by COA
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point NA
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note
Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
Asymmetric hydrogenation of ketones and phosphinylketimines.
Michael addition of Grignard reagents to ",$-unsaturated esters and thioesters.
Boration of ",$-unsaturated esters and nitriles.
Reaction of aryl halides with ammonia.
Cu-catalyzed reduction of activated C=C bonds with PMHS.
Regio- and enantioselective hydroboration of vinyl arenes.
Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
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