Details

Item Description Structure
Catalog 8091 CAS 213697-53-1
Product Name 2-(Dicyclohexylphosphino)-2'-(N,N-dimethylamino)biphenyl
Other Name DavePhos,2-(DICYCLOHEXYLPHOSPHINO)-2'-(DIMETHYLAMINO)BIPHENYL;2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL;2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHY&;2-Dicyclohexylphosphino-2'-(N,;2-(Dicyclohexylphosphino)-2'-(N,N-dimethylamino)biphenyl,98%DavePhos;2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)-;
Purity 98% ee NA
Molecular Formula C26H36NP
Molecular Weight 393.55
Color and Form white xtl.
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 115-119C
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Ligand used in the Pd-catalyzed Suzuki coupling and animation of unactivated aryl chlorides.
The reactions generally occur at room temperature and give high yields of product.
2. Ligand used in Pd-catalyzed C-N bond formation. A general synthesis of N6-aryl-2'-
deoxyadenosine analogues.
3. Ligand used in Pd-catalyzed N-arylation of indoles.
4. Ligand used in Pd-catalyzed synthesis of aryl-tert-butyl ethers.
5. Effective ligand in the Pd-catalyzed arylation of ester enolates.
6. Ligand employed in arylation of ketone enolates using ortho-halo nitrobenezenes.
7. Ligand employed in the amination of aryl nonaflates using Pd catalysts.
8. Ligand used for cascade alkenyl amination/Heck reaction for the synthesis of indoles.
9. Ligand used in Pd-catalyzed Kumada-Corriu cross coupling at low temperatures.
10. Ligand used in Rh-catalyzed intramolecular hydroamination of unactivated terminal and internal
alkenes with primary and secondary amines.
11. Ligand used in Au-catalyzed cycloisomerization of allenes
References:
1. J. Am. Chem. Soc., 1998, 120, 9722.
2. J. Am. Chem. Soc., 1999, 121, 6090.
3. Org. Lett., 2000, 2, 1403.
4. J. Org. Chem., 2001, 66, 2498.
5. J. Am. Chem. Soc., 2001, 123, 7996.
6. J. Am. Chem. Soc., 2002, 124, 15168.
7. J. Org. Chem., 2003, 68, 9563.
8. Chem. Eur. J., 2005, 11, 2276
9. J. Am. Chem. Soc., 2007, 129, 3844.
10. J. Am. Chem. Soc., 2008, 130, 1570.
11. Adv. Synth. Catal., 2009, 351, 576.

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