Details

Item Description Structure
Catalog 8099 CAS 240417-00-9
Product Name 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
Other Name 2-DIMETHYLAMINO-2'-(DIPHENYLPHOSPHINO)BIPHENYL;2-(DIPHENYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)BIPHENYL;2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl,98%;(N,N-DIMETHYLAMINO)BIPHENYL;[1,1''-BIPHENYL]-2-AMINE, 2''-(DIPHENYLPHOSPHINO)-N,N-DIMETHYL-;2-Dimethylamino-2'-(diphenylphosphino)biphenyl;2-Diphenylphosphino-2`-dimethylaminobiphenyl;PhDavePhos
Purity 98% ee NA
Molecular Formula C26H24NP
Molecular Weight 381.46
Color and Form white to yellow powder, crystals, crystalline
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 126-128 C
Stability Yes
Risk 36/37/38 Safety 37/39-26-36/37/39 Hazard Xi
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl
bromides.
2. Ligand employed in the coupling of enantiomerically pure cis-dimethylpiperazine with
bromobenzene. Epimerization was not observed.
3. Ligand employed for the Pd-catalyzed heteroarylation of acetone.
4. Ligand used for the Cu-catalyzed phosphorylation of alcohols.
References:
1. Angew. Chem. Int. Ed., 2005, 44, 6173.
2. Synlett., 2006, 2941.
3. Org. Lett., 2005, 7, 3271.
4. Org. Lett., 2009, 11, 4160.
5. Chem. Sci., 2011, 2, 27-50.

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