Details

Item Description Structure
Catalog 8393 CAS 38596-61-1
Product Name Carbonylbis(trifluoroacetato)bis(triphenylphosphine)ruthenium(II) methanol adduct
Other Name NA
Purity 99% ee NA
Molecular Formula C41H30F6O5P2Ru
Molecular Weight 879.71
Color and Form orange xtl
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 236-237 C
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Catalyst for the dehydrogenation of alcohols into aldehydes and ketones.
2. Catalyst for regioselective reductive hydroxymethylation of alkynes with paraformaldehyde.

1. Hydroacylation of 2-Butyne from the Alcohol or Aldehyde Oxidation Level via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation. Williams, V. M. et al. Tetrahedron 65, 5024, (2009)
2. Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation. Patman, R. L. et al. J. Am. Chem. Soc. 131th ed.,, 2066, (2009)

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DISCLAIMER:
Products under Patent are not for ultimate sale in the country where patent has not expired. All liability for violation of Patent laws will be to the account of the Purchaser.
Other 1,4-Bis(diphenylphosphino)butane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, dichloromethane adduct,98% 59831-02-6 Dichloro(1,3-bis(diphenylphosphino)propane)palladium(II),98% (DPPP)PdCl2 157772-65-1 1,1'-Bis(di-i-propylphosphino)ferrocene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate,98% 13965-03-2 trans-Dichlorobis(triphenylphosphine)palladium(II),98% (PPh3)2PdCl2 99326-34-8 1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate,98% 14588-08-0 Diacetatobis(triphenylphosphine)palladium(II),98% (PPh3)2Pd(OAc)2 120967-70-6 1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate 14221-01-3 Tetrakis(triphenylphosphine)palladium (0),98% Pd(PPh3)4 73468-85-6 Hydroxy(1,5-cyclooctadiene)rhodium(I) dimer,97% [Rh(COD)(OH)]2 32005-36-0 Bis(dibenzylideneacetone)palladium (0), Pd(dba)2 12279-09-3 Chlorobis(cyclooctene)rhodium(I) dimer,98% 51364-51-3 Tris(dibenzylideneacetone)dipalladium (0), Pd2(dba)3 34767-55-0 Acetylacetonatobis(cyclooctene)rhodium(I),97% 52522-40-4 Tris(dibenzylideneacetone)dipalladium (0) chloroform adduct, Pd2(dba)3 CHCl3 36620-11-8 Bis(norbornadiene)rhodium(I) tetrafluoroborate,96% [Rh(NBD)2]+BF4- 14592-56-4 Dichlorobis(acetonitrile)palladium(II),98% (CH3CN)2PdCl2 12257-42-0 Chloronorbornadiene rhodium(I) dimer,98% [Rh(NBD)Cl]2 12081-16-2 Chlorobis(ethylene)rhodium(I) dimer,98% [Rh(C2H4)2Cl]2 12107-56-1 Dichloro(1,5-cyclooctadiene)palladium(II),98% (COD)PdCl2 12082-47-2 Acetylacetonatobis(ethylene)rhodium(I),98% 14267-08-4 cis-Dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II),98% 178879-60-2 Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(R-DOSP)4 3375-31-3 Palladium(II) acetate,98% Pd3(OAc)6 179162-34-6 Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(S-DOSP)4 42196-31-6 Palladium(II) trifluoroacetate,97% Pd(CF3COO)2 12354-85-7 Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer,98% (Cp*RhCl2)2 115826-95-4 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),98% (R-BINAP)PdCl2 14284-92-5 Rhodium(III) acetylacetonate,98% Rh(CH3COCHCOCH3)3 127593-28-6 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),98% (S-BINAP)PdCl2 17185-29-4 Hydridocarbonyltris(triphenylphosphine)rhodium(I),98% 172418-32-5 trans-Di(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II),97% 13938-94-8 Chlorocarbonylbis(triphenylphosphine)rhodium(I),98% 31277-98-2 Bis[1,2-bis(diphenylphosphino)ethane]palladium (0),98% Pd(DPPE)2 14523-22-9 Chlorodicarbonylrhodium(I) dimer 444910-17-2 Dichloro(di-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II),97% 14874-82-9 Dicarbonylacetylacetonato rhodium(I),98% 14024-61-4 Palladium(II) acetylacetonate,98% 31126-95-1 Rhodium(II) trifluoroacetate dimer, Rh2(CF3COO)4 113822-11-0 cis-Dimethyl(N,N,N',N'-tetramethylethylenediamine)palladium(II),98% 10/1/7647 Palladium(II) chloride,98% PdCl2 13444-94-5 Palladium(II) bromide,98% PdBr2 7790-38-7 Palladium(II) iodide,98% PdI2 14220-64-5 Dichlorobis(benzonitrile)palladium(II),98% (C6H5CN)2PdCl2 205319-10-4 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II),98% 185812-86-6 Di-bromobis(tri-t-butylphosphino)dipalladium(I) 33309-88-5 Bis(tricyclohexylphosphine)palladium (0),98% Pd(PCy3)2 917511-90-1 Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct,98% 215788-65-1 Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium (II),98% 123333-45-9 [P,P'-1,3-Bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium (0)