Details

Item Description Structure
Catalog 8127 CAS 490023-37-5
Product Name ?(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine
Other Name (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE;(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE;(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS);(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%;(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a]dinaphthalen-4-yl)MethylaMine
Purity 99% ee 99%
Molecular Formula C28H22NO2P
Molecular Weight 435.45
Color and Form white pwdr.
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 155-159 C
Stability Yes
Risk 36/37/38 Safety 26-36/37/39 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines
The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro--aminoacid esters (For (Z) isomer
References:
1. J. Am. Chem. Soc., 2010, 132, 2124.
2. J. Am. Chem. Soc., 2002, 124, 14552.

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