Details

Item Description Structure
Catalog 8387 CAS 104439-77-2
Product Name 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)--hydrotetracarbonyldiruthenium(II)
Other Name SHVO'S CATALYST
Purity 98% ee NA
Molecular Formula C62H42O6Ru2
Molecular Weight 1085.13
Color and Form orange pwdr
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 223-227 C
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Shvos Catalyst
In catalytic asymmetric synthesis enzyme-mediated kinetic resolution is an important area. Lipases are particularly successful in kinetic resolutions and hence are manufactured on a commercial scale...
Keywords: Asymmetric synthesis, Catalysis, Epimerizations, Immobilization, Isomerizations, Organic synthesis, Oxidations, Reductions, Sol-gel, Transesterifications
1. Prabhakaran, R. Synlett, 2048, (2004)
2. Combination of enzymes and metal catalysts. A powerful approach in asymmetric catalysis. Pmies, O.; B?ckvall, J.-E. Chem. Rev. 103, 3247, (2003)
Merck 14,8483
Technical Notes:
1. In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral
acetates.
2. Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.
3. Coversion of secondary amines to primary amines in the presence of ammonia.
4. Co-catalyt for aerobic lactonization of diols.
References:
1. Org. Lett., 2000, 2, 2487.
2. Org. Lett., 2001, 3, 1209.
3. J. Org. Chem., 2002, 67, 9006.
4. Chem. Eur. J., 2011, 17, 4705.
5. Chem. Eur. J., 2011, 17, 12596.

 

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DISCLAIMER:
Products under Patent are not for ultimate sale in the country where patent has not expired. All liability for violation of Patent laws will be to the account of the Purchaser.
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