Details

Item Description Structure
Catalog 8389 CAS 12289-94-0
Product Name ?Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)
Other Name NA
Purity 97% ee NA
Molecular Formula C16H26Ru
Molecular Weight 319.45
Color and Form tan to brown pwdr.
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 81.7-82.4 C(lit.)
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
2. -ketoester reduction.
3. Anti-Markovnikov addition of amides to alkynes.
4. Anti-Markovnikov hydroamination of vinylarenes.
5. Catalyst for the addition of amides to alkynes.
References:
1. Tetrahedron Lett.,1995, 36, 4801.
2. Acros Organics Acta, 1995, 1, 4. (review)
3. J. Am. Chem. Soc., 2003, 125, 9570.
4. Advanced Synthesis and Catalysis, 2003, 345(1+2), 261.
5. Angew. Chem. Int. Ed., 2005, 44, 4042.
6. J. Am. Chem. Soc., 2004, 126, 2702

CIF ?PRICE
5g/ $0.00 10g/ $ 0.00 kg/$0.00 enquire more please contact us PDF file


DISCLAIMER:
Products under Patent are not for ultimate sale in the country where patent has not expired. All liability for violation of Patent laws will be to the account of the Purchaser.
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