Details

Item Description Structure
Catalog 8118 CAS 133545-16-1
Product Name ?(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
Other Name R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine);(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(R)-MeO-BIPHEP;(R)-(+)-MeO-BIPHEP
Purity 97% ee 99%
Molecular Formula C38H32O2P2
Molecular Weight 582.53
Color and Form off-white powder
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 213-216 C
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid
derivatives.
Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.
Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
Rhodium-catalyzed carboncyl Z-dienylation.
References:
1. Adv. Synth. Catal., 2004, 346, 842.
2. Org. Lett., 2006, 8, 4573.
3. Org. Process Res. Devel., 2001, 5, 438.
4. J. Am. Chem. Soc., 2003, 125, 10536.
5. Org. Lett., 2009, 11, 4200.
6. J. Org. Chem., 2007, 72 , 3875.
7. J. Am. Chem. Soc., 2006, 128, 16040.

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