Details

Item Description Structure
Catalog 8137 CAS 148461-14-7
Product Name (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole
Other Name (S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE;Diphenylphosphinophenylmethylethyldihydrooxazole
Purity 98% ee 99%
Molecular Formula C24H24NOP
Molecular Weight 373.43
Color and Form White crystalline powder
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 85-90 C
Stability Yes
Risk 36/37/38 Safety 37/39-26 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Chiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to
the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
References:
1. Angew. Chem. Int. Ed., 1998, 37, 2897.
2. Angew. Chem. Int. Ed., 1996, 35, 200.
3. Acc. Chem. Res., 2000, 33, 336.
4. Eur. J. Org. Chem., 2011, 31, 6288.

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