Details

Item Description Structure
Catalog 8394 CAS 15243-33-1
Product Name Ruthenium carbonyl
Other Name NA
Purity 99% ee NA
Molecular Formula C12O12Ru3
Molecular Weight 639.34
Color and Form orange xtl.
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point ?150C dec
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Catalyst for the conversion of enynes to catechol derivatives.
2. Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
3. 3-Component couplings.
4. Reaction of ,-unsaturated imines with carbon monoxide and alkenes to form ,-unsaturated -butyroactams.
5. Ester decarboxylation.
6. Catalyst for hydroamination and C-H bond activation.
7. Used in sp3C-H bond arylation7 and carbonylation.
8. Ru/halide catalytic system for C-C b

References:
1. Tetrahedron Lett. 22, 1541, (1981)
2. J. Am. Chem. Soc. 106, 4647, (1984)
3. J. Chem. Soc., Chem. Commun., 1286, (1984)
4. J. Chem. Soc., Dalton Trans., 2649, (1988)
5. Ragaini, F. et al. Organometallics 18, 928, (1999)
Ragaini, F. et al. Organometallics 18, 929, (1999)
Ru-catalyzed intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide leading to alpha-pyrones. Org. Lett. 9, 587, (2007)
FT-IR 2 (3), 4592:B / FT-IR 1 (2), 1299:D / RegBook 1 (2), 3143:B

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