Item Description | Structure | ||||||||||||||||
Catalog | 8175 | CAS | 162291-01-2 | ![]() |
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Product Name | (S)-(+)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine | ||||||||||||||||
Other Name | NA | ||||||||||||||||
Purity | 97% | ee | 99% | ||||||||||||||
Molecular Formula | C36H44FeP2 | ||||||||||||||||
Molecular Weight | 594.59 | ||||||||||||||||
Color and Form | orange pwdr | ||||||||||||||||
Package | 5g/10g and more Bulk Ordering Package | ||||||||||||||||
Solubility | NA | ||||||||||||||||
Melting point | NA | ||||||||||||||||
Stability | Yes | ||||||||||||||||
Risk | R20/22... | Safety | S26/S45 | Hazard | NA | ||||||||||||
spectrometry | Conforms to structure | ||||||||||||||||
HPLC | Conforms to structure | ||||||||||||||||
Note | Only for research purposes only | ||||||||||||||||
Technical Note | |||||||||||||||||
Useful as a ligand in Pd-catalyzed C-N bond-forming reactions. Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides. Asymmetric hydrogenation of ketones and phosphinylketimines. Michael addition of Grignard reagents to ",$-unsaturated esters and thioesters. Boration of ",$-unsaturated esters and nitriles. Reaction of aryl halides with ammonia. Cu-catalyzed reduction of activated C=C bonds with PMHS. Regio- and enantioselective hydroboration of vinyl arenes. Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes. 1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands. References: 1. Solvias owns the patent rights for Strem products 26-1000, 26-1001, 26-1200, 26-1201, 26-1230, 26-1101, and for the Ir and Rh complexes of the aforementioned products, including the complexes of 26-1210 and 26-1211. 2. C&E News, July 22, 1996, 38. 3. Angew. Chem. Int Ed., 1996, 35, 1475. 4. J. Org. Chem., 1972, 37, 3052. 5. J. Am. Chem. Soc., 1994, 116, 4062. 6. Inorg. Chim. Acta., 1994, 222, 213. 7. Organometallics, 1996, 15, 860. 8. Helv. Chim. Acta., 1995, 78, 883. 9. European Patents; EP 624587 A2 941117, EP 612758 A1 940831, EP 564406 A1 931006. 10. Comprehensive Asymmetric Catalysis, 1999, Chapter 6.1, pg. 199-207. 11. Topics in Catalysis, March 2002, 19. (review) 12. J. Am. Chem. Soc., 2004, 126, 10248. 13. (a) Angew. Chem. Int. Ed,, 2007, 46, 7651. (b) Adv. Synth. Catal., 2002, 343, 68. 14. Angew. Chem. Int. Ed., 2005, 44, 2752. 15. Angew. Chem. Int. Ed., 2007, 47, 145. 16. J. Am. Chem. Soc., 2006, 128, 10028. 17. (a) Angew. Chem. Int. Ed., 2003, 42, 4793. (b) Angew. Chem. Int. Ed., 2006, 45, 2785. (c) J. Am. Chem. Soc., 2009, 131, 10386. 18. Angew. Chem. Int. Ed., 2006, 45, 17674. (review) 19. J. Am. Chem. Soc., 2004, 126, 9200. 20. Proc. Natl. Acad. Sci. U.S.A., 20 |
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CIF ?PRICE | |||||||||||||||||
5g/ $0.00 10g/ $ 0.00 kg/$0.00 | enquire more please contact us | PDF file |