Details

Item Description Structure
Catalog 8124 CAS 185449-86-9
Product Name (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine
Other Name (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE;(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%;(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
Purity 98% ee 99%
Molecular Formula C24H22NO2P
Molecular Weight 387.41
Color and Form off-white pwdr
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 228-229C, spec. rotation +636 (c 0.30, CH2Cl2)
Stability Yes Stability: moisture sensitive
Risk 36/37/38 Safety 26-36/37/39 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino
acids, enamides, and unsaturated acids.
Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in
the 1 or 3 position.
Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
References:
1. J. Am. Chem. Soc., 2000, 122, 11539.
2. Adv. Synth. Catal., 2003, 345, 308.
3. Adv. Synth. Catal., 2002, 344, 1003.
4. Chem. Comm, 1999, 741.
5. Eur. J. Inorg. Chem., 2002, 2569.
6. J. Am. Chem. Soc., 2008, 130, 3734.

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