Item Description Structure
Catalog 8099 CAS 240417-00-9
Product Name 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
Other Name 2-DIMETHYLAMINO-2'-(DIPHENYLPHOSPHINO)BIPHENYL;2-(DIPHENYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)BIPHENYL;2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl,98%;(N,N-DIMETHYLAMINO)BIPHENYL;[1,1''-BIPHENYL]-2-AMINE, 2''-(DIPHENYLPHOSPHINO)-N,N-DIMETHYL-;2-Dimethylamino-2'-(diphenylphosphino)biphenyl;2-Diphenylphosphino-2`-dimethylaminobiphenyl;PhDavePhos
Purity 98% ee NA
Molecular Formula C26H24NP
Molecular Weight 381.46
Color and Form white to yellow powder, crystals, crystalline
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 126-128 C
Stability Yes
Risk 36/37/38 Safety 37/39-26-36/37/39 Hazard Xi
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl
2. Ligand employed in the coupling of enantiomerically pure cis-dimethylpiperazine with
bromobenzene. Epimerization was not observed.
3. Ligand employed for the Pd-catalyzed heteroarylation of acetone.
4. Ligand used for the Cu-catalyzed phosphorylation of alcohols.
1. Angew. Chem. Int. Ed., 2005, 44, 6173.
2. Synlett., 2006, 2941.
3. Org. Lett., 2005, 7, 3271.
4. Org. Lett., 2009, 11, 4160.
5. Chem. Sci., 2011, 2, 27-50.

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