Details

Item Description Structure
Catalog 8188 CAS 277306-29-3
Product Name (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine
Other Name NA
Purity 97% ee 99%
Molecular Formula C32H40FeP2
Molecular Weight 542.46
Color and Form orange pwdr
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point NA
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

References:
1. Solvias owns the patent rights for Strem products 26-1000, 26-1001, 26-1200, 26-1201, 26-1230,
26-1101, and for the Ir and Rh complexes of the aforementioned products, including the
complexes of 26-1210 and 26-1211.
2. C&E News, July 22, 1996, 38.
3. Angew. Chem. Int Ed., 1996, 35, 1475.
4. J. Org. Chem., 1972, 37, 3052.
5. J. Am. Chem. Soc., 1994, 116, 4062.
6. Inorg. Chim. Acta., 1994, 222, 213.
7. Organometallics, 1996, 15, 860.
8. Helv. Chim. Acta., 1995, 78, 883.
9. European Patents; EP 624587 A2 941117, EP 612758 A1 940831, EP 564406 A1 931006.
10. Comprehensive Asymmetric Catalysis, 1999, Chapter 6.1, pg. 199-207.
11. Topics in Catalysis, March 2002, 19. (review)
12. J. Am. Chem. Soc., 2004, 126, 10248.
13. (a) Angew. Chem. Int. Ed,, 2007, 46, 7651. (b) Adv. Synth. Catal., 2002, 343, 68.
14. Angew. Chem. Int. Ed., 2005, 44, 2752.
15. Angew. Chem. Int. Ed., 2007, 47, 145.
16. J. Am. Chem. Soc., 2006, 128, 10028.
17. (a) Angew. Chem. Int. Ed., 2003, 42, 4793. (b) Angew. Chem. Int. Ed., 2006, 45, 2785.
(c) J. Am. Chem. Soc., 2009, 131, 10386.
18. Angew. Chem. Int. Ed., 2006, 45, 17674. (review)
19. J. Am. Chem. Soc., 2004, 126, 9200.
20. Proc. Natl. Acad. Sci. U.S.A., 2004, 101, 5455.

Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
Asymmetric hydrogenation of ketones and phosphinylketimines.
Michael addition of Grignard reagents to ",$-unsaturated esters and thioesters.
Boration of ",$-unsaturated esters and nitriles.
Reaction of aryl halides with ammonia.
Cu-catalyzed reduction of activated C=C bonds with PMHS.
Regio- and enantioselective hydroboration of vinyl arenes.
Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.

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