Details

Item Description Structure
Catalog 8378 CAS 309735-86-2
Product Name Dimethylammonium dichlorotri(-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)
Other Name [NH2Me2][{RuCl((S)-tolbinap)}2(-Cl)3]
Purity 97% ee 99%
Molecular Formula C98H87Cl5NP4Ru2
Molecular Weight 1782.05
Color and Form brown pwdr
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point NA
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note
Application
Catalyst system for asymmetric hydrogenation
Takasago Ligands and Complexes for Asymmetric Reactions
Technical Notes:
1. (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to
form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic
activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI
CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of
functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl,
ester, amide or thioester.
2. Useful ligand in asymmetric Heck processes.
3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
4. Ligand employed in rhodium-catalyzed 1,4-additions to enones.
5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol
reaction.
7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
10. Ligand employed in palladium-catalyzed synthesis of chiral allenes.
11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid
derivatives.
12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic
enones.
14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl
transfer using a Si-B linkage.
16.Catalyst system for asymmetric hydrogenation.
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