Details

Item Description Structure
Catalog 8001 CAS 35238-97-2
Product Name (1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)
Other Name NA
Purity 97% ee NA
Molecular Formula C45H44Cl2F6P3Rh
Molecular Weight 965.55
Color and Form Get details by COA
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 215 C(lit.)
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note
Catalyst for:
Polycyclotrimerization reactions1
Hydrosilylation and hydrogenation reactions2
Hydroformylation reactions3
Regioselective di- and trisilylation reactions4
Mannich and nitro-Mannich reactions5
Reductive alkylation reactions6

1. Shi, J.; et al. Macromolecules 43, 680, (2010)
2. Voutchkova, A. M.; et al. J. Organomet. Chem. 693, 1815, (2008)
3. Rosales, M.; et al. J. Mol. Catal. A: Chem. 270, 250, (2007)
4. Regioselectively trisilylated hexopyranosides through homogeneously catalyzed silane alcoholysis. Chung, M.-K.; Schlaf, M. J. Am. Chem. Soc. 127, 18085, (2005)
5. Direct Mannich and nitro-Mannich reactions with non-activated imines: AgOTf-catalyzed addition of pronucleophiles to ortho-alkynylaryl aldimines leading to 1,2-dihydroisoquinolines. Asao, N.; et al. Angew. Chem. Int. Ed. Engl. 44, 5526, (2005)
6. Margalef-Catala, R.; et al. Tetrahedron Lett. 41, 6583, (2000)
Principles determining the structure of high-pressure forms of metals: The structures of cesium(IV) and cesium(V). Polyhedron 8, 1431, (1989)
Chem. Lett., 881, (1988)
CIF ?PRICE
5g/ $0.00 10g/ $ 0.00 kg/$0.00 enquire more please contact us PDF file


DISCLAIMER:
Products under Patent are not for ultimate sale in the country where patent has not expired. All liability for violation of Patent laws will be to the account of the Purchaser.
Other 1,4-Bis(diphenylphosphino)butane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, dichloromethane adduct,98% 59831-02-6 Dichloro(1,3-bis(diphenylphosphino)propane)palladium(II),98% (DPPP)PdCl2 157772-65-1 1,1'-Bis(di-i-propylphosphino)ferrocene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate,98% 13965-03-2 trans-Dichlorobis(triphenylphosphine)palladium(II),98% (PPh3)2PdCl2 99326-34-8 1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate,98% 14588-08-0 Diacetatobis(triphenylphosphine)palladium(II),98% (PPh3)2Pd(OAc)2 120967-70-6 1,5-Cyclooctadiene(hydroquinone)rhodium(I) tetrafluoroborate 14221-01-3 Tetrakis(triphenylphosphine)palladium (0),98% Pd(PPh3)4 73468-85-6 Hydroxy(1,5-cyclooctadiene)rhodium(I) dimer,97% [Rh(COD)(OH)]2 32005-36-0 Bis(dibenzylideneacetone)palladium (0), Pd(dba)2 12279-09-3 Chlorobis(cyclooctene)rhodium(I) dimer,98% 51364-51-3 Tris(dibenzylideneacetone)dipalladium (0), Pd2(dba)3 34767-55-0 Acetylacetonatobis(cyclooctene)rhodium(I),97% 52522-40-4 Tris(dibenzylideneacetone)dipalladium (0) chloroform adduct, Pd2(dba)3 CHCl3 36620-11-8 Bis(norbornadiene)rhodium(I) tetrafluoroborate,96% [Rh(NBD)2]+BF4- 14592-56-4 Dichlorobis(acetonitrile)palladium(II),98% (CH3CN)2PdCl2 12257-42-0 Chloronorbornadiene rhodium(I) dimer,98% [Rh(NBD)Cl]2 12081-16-2 Chlorobis(ethylene)rhodium(I) dimer,98% [Rh(C2H4)2Cl]2 12107-56-1 Dichloro(1,5-cyclooctadiene)palladium(II),98% (COD)PdCl2 12082-47-2 Acetylacetonatobis(ethylene)rhodium(I),98% 14267-08-4 cis-Dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II),98% 178879-60-2 Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(R-DOSP)4 3375-31-3 Palladium(II) acetate,98% Pd3(OAc)6 179162-34-6 Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(S-DOSP)4 42196-31-6 Palladium(II) trifluoroacetate,97% Pd(CF3COO)2 12354-85-7 Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer,98% (Cp*RhCl2)2 115826-95-4 Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),98% (R-BINAP)PdCl2 14284-92-5 Rhodium(III) acetylacetonate,98% Rh(CH3COCHCOCH3)3 127593-28-6 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),98% (S-BINAP)PdCl2 17185-29-4 Hydridocarbonyltris(triphenylphosphine)rhodium(I),98% 172418-32-5 trans-Di(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II),97% 13938-94-8 Chlorocarbonylbis(triphenylphosphine)rhodium(I),98% 31277-98-2 Bis[1,2-bis(diphenylphosphino)ethane]palladium (0),98% Pd(DPPE)2 14523-22-9 Chlorodicarbonylrhodium(I) dimer 444910-17-2 Dichloro(di-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II),97% 14874-82-9 Dicarbonylacetylacetonato rhodium(I),98% 14024-61-4 Palladium(II) acetylacetonate,98% 31126-95-1 Rhodium(II) trifluoroacetate dimer, Rh2(CF3COO)4 113822-11-0 cis-Dimethyl(N,N,N',N'-tetramethylethylenediamine)palladium(II),98% 10/1/7647 Palladium(II) chloride,98% PdCl2 13444-94-5 Palladium(II) bromide,98% PdBr2 7790-38-7 Palladium(II) iodide,98% PdI2 14220-64-5 Dichlorobis(benzonitrile)palladium(II),98% (C6H5CN)2PdCl2 205319-10-4 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II),98% 185812-86-6 Di-bromobis(tri-t-butylphosphino)dipalladium(I) 33309-88-5 Bis(tricyclohexylphosphine)palladium (0),98% Pd(PCy3)2 917511-90-1 Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct,98% 215788-65-1 Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium (II),98% 123333-45-9 [P,P'-1,3-Bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium (0)