Details

Item Description Structure
Catalog 8363 CAS 374067-50-2
Product Name Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]
Other Name (R)-Ru(OAc)2(DM-BINAP)
Purity 98% ee 99%
Molecular Formula C56H54O4P2Ru
Molecular Weight 954.04
Color and Form dark brown
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point NA
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

(R)-Ru(OAc)2(DM-BINAP) Catalyst for:
Catalyst system used for asymmetric hydrogenation
Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
Asymmetric reduction of (nitro)(phenyl)propene
Asymmetric synthesis of chiral d-lactones via hydrogenation
Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene

Reference:
A General Access to Zaragozic Acids: Total Synthesis and Structure Elucidation of Zaragozic Acid D and Formal Syntheses of Zaragozic Acids A and C Wang, Y.; Metz, P. Chem. Eur. J. 17, 3335-3337, (2011)
Total synthesis of (+)-papulacandin D Denmark, S. E.; et al. Tetrahedron 66, 4745-4759, (2010)
Mechanism of catalytic asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline using Ru(CH3COO)2[(S)-binap] Tsukamoto, M.; et al. Tetrahedron 62, 5448-5453, (2006)
A novel asymmetric reduction of nitroolefin 2-nitro-1-phenyl-1-propene by using BINAP-ruthenium(II) complexes Li, Y.; Izumi, T. J. Chem. Res. Synop., 128-129, (2003)
Asymmetric synthesis of chiral d-lactones using BINAP-ruthenium(II) complex hydrogenation catalysts Li, Y.; Izumi, T. J. Chem. Res. Synop., 567-569, (2002)
Synthesis of Chiraphos via asymmetric hydrogenation of 2,3-bis(diphenylphosphinoyl)buta-1,3-diene Beghetto, V.; et al. Chem. Commun., 155-156, (2000)
J. Org. Chem., 1994, 59, 297.

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