Details

Item Description Structure
Catalog 8128 CAS 415918-91-1
Product Name (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct
Other Name (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT;(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-amine, (11bS);(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
Purity 96% ee 99%
Molecular Formula C37H32Cl2NO2P
Molecular Weight 624.54
Color and Form white pwdr
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 102-103 C
Stability Yes
Risk 36/37/38 Safety 26-36/37/39 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
allylic esters.
Asymmetric hydrogenation.
Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
Asymmetric hydrovinylation.
Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,
and Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclpropanes.
References:
1. Angew. Chem. Int. Ed., 1997, 36, 2620.
2. J. Am. Chem. Soc., 2002, 124, 15164.
3. J. Am. Chem. Soc., 2003, 125, 3426.
4. Org. Lett., 2005, 7, 1093.
5. J. Am. Chem. Soc., 2007, 129, 7720.
6. Acc. Chem. Res., 2007, 40, 1267.
7. Org. Lett., 2008, 10, 1815.
8. Synthesis., 2009, 2089.
9. (a) Angew. Chem. Int. Ed., 2008, 47, 6055. (b) Chem. Eur. J., 2009, 15, 8692.

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