Details

Item Description Structure
Catalog 8176 CAS 494227-32-6
Product Name (R)-(+)-1-[(R)-2-(2'-Dicyclohexylphosphinophenyl)ferrocenyl]ethyldi(bis-3,5-trifluoromethylphenyl)phosphine
Other Name NA
Purity 97% ee 99%
Molecular Formula C46H44F12FeP2
Molecular Weight 942.62
Color and Form orange pwdr.
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point NA
Stability Yes
Risk R20/22... Safety S26/S45 Hazard NA
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note
Technical Notes:
Ligand for Rh and Ru-catalzyed hydrogenation of alkenes and ketones.
Rh-catalyzed intermolecular [4+2].
Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and
ketones.
References:
1. (a) Adv. Synth. Catal., 2003, 345, 160. (b) Org. Lett., 2006, 8, 2413.
2. Angew. Chem., 2008, 120, 5904.
3. J. Am. Chem., 2006, 128, 16448.
CIF ?PRICE
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DISCLAIMER:
Products under Patent are not for ultimate sale in the country where patent has not expired. All liability for violation of Patent laws will be to the account of the Purchaser.
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