Details

Item Description Structure
Catalog 8107 CAS 84680-95-5
Product Name 1,1'-Bis(di-t-butylphosphino)ferrocene
Other Name 1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE;BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON;1,1'-Bis(di-t-butylphosphino)ferrocene,min.98%;1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98%;1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98%;1,1'-Bis(di-tert-butylphosphino)ferrocene ,98%;98% DtBPF
Purity 98% ee NA
Molecular Formula C26H44FeP2
Molecular Weight 474.42
Color and Form Get details by COA
Package 5g/10g and more Bulk Ordering Package
Solubility NA
Melting point 181-182C (dec.)
Stability Yes
Risk 36/37/38 Safety 22-24/25-36/37/39-26 Hazard Xi
spectrometry Conforms to structure
HPLC Conforms to structure
Note Only for research purposes only
Technical Note

Technical Notes:
1. Ligand used in the palladium-catalyzed -arylation of ketones.
2. Ligand used in the palladium-catalyzed heteroannulation of 1,3-dienes to form -alkylidene--butyrolactones.
3. 1-Aminoindol derivatives via Pd-catalyzed intramolecular cyclization.
4. Indoles via regioselective Pd-catalyzed coupling of 2-Chloroanilines with internal alkynes.
5. Synthesis of hetero-biaryl compounds containing a NH2 via Suzuki-Miyaura reaction.
References:
1. J. Am. Chem. Soc., 1999, 121, 1473.
2. J. Org. Chem., 2000, 65, 1525.
3. Angew. Chem. Int. Ed., 2000, 39, 2501.
4. Org. Lett., 2004, 6, 4129.
5. Tetrahedron Lett., 2005, 46, 3573.

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Products under Patent are not for ultimate sale in the country where patent has not expired. All liability for violation of Patent laws will be to the account of the Purchaser.
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